Isotopic evolution of planetary crusts by hypervelocity impacts evidenced by Fe in microtektites.

Fractionation effects related to evaporation and condensation had a major impact on the current elemental and isotopic composition of the Solar System. Although isotopic fractionation of moderately volatile elements has been observed in tektites due to impact heating, the exact nature of the processes taking place during hypervelocity impacts remains poorly understood. By studying Fe in microtektites, here we show that impact events do not simply lead to melting, melt expulsion and evaporation, but involve a convoluted sequence of processes including condensation, variable degrees of mixing between isotopically distinct reservoirs and ablative evaporation during atmospheric re-entry. Hypervelocity impacts can as such not only generate isotopically heavy, but also isotopically light ejecta, with δ56/54Fe spanning over nearly 5‰ and likely even larger variations for more volatile elements. The mechanisms demonstrated here for terrestrial impact ejecta modify our understanding of the effects of impact processing on the isotopic evolution of planetary crusts.

The formation of impact coesite.

Coesite in impact rocks is traditionally considered a retrograde product formed during pressure release by the crystallisation of an amorphous phase (either silica melt or diaplectic glass). Recently, the detailed microscopic and crystallographic study of impact ejecta from Kamil crater and the Australasian tektite strewn field pointed in turn to a different coesite formation pathway, through subsolidus quartz-to-coesite transformation. We report here further evidence documenting the formation of coesite directly from quartz. In Kamil ejecta we found sub-micrometric single-coesite-crystals that represent the first crystallization seeds of coesite. Coesite in Australasian samples show instead well-developed subeuhedral crystals, growing at the expenses of hosting quartz and postdating PDF deformation. Coesite (010) plane is most often parallel to quartz {10-11} plane family, supporting the formation of coesite through a topotactic transformation. Such reaction is facilitated by the presence of pre-existing and shock-induced discontinuities in the target. Shock wave reverberations can provide pressure and time conditions for coesite nucleation and growth. Because discontinuities occur in both porous and non-porous rocks and the coesite formation mechanism appears similar for small and large impacts, we infer that the proposed subsolidus transformation model is valid for all types of quartz-bearing target rocks.

A unique CO-like micrometeorite hosting an exotic Al-Cu-Fe-bearing assemblage - close affinities with the Khatyrka meteorite.

We report the discovery of a unique micrometeorite, containing an exotic Al-Cu-Fe alloy composed of two intermixed phases: khatyrkite (CuAl2) and stolperite (CuAl) and both containing minor Fe (<1.4 wt%). These phases are dendritic and rapidly co-crystallized at the binary system's peritectic (~550 °C). The host micrometeorite is an otherwise typical S-type micro-porphyritic cosmic spherule containing relict olivine (Fo76-90, Cr2O3: 0.01-0.56 wt%, MnO: 0.03-0.32 wt% and CaO: 0.09-0.22 wt%) and a cumulate layered texture. These properties suggest the micrometeorite is derived from a carbonaceous chondrite (best matched to a CO chondrite) and entered the atmosphere a high speed (~16 kms-1), implying an origin from a highly eccentric orbit. This particle represents the second independent discovery of naturally occurring intermetallic Al-Cu-Fe alloys and is thus similar to the previously reported Khatyrka meteorite - a CV chondrite containing near-identical alloys and the only known natural quasicrystals. We did not observe quasicrystalline phases in this micrometeorite, likely due to the low amounts of Fe in the alloy, insufficient to stabilize quasicrystals. Our discovery confirms the existence of Al-Cu-Fe intermetallic alloys on chondritic parent bodies. These unusual phases require a currently unexplained formation process, we tentatively suggest this could represent the delivery of exotic interstellar material to the inner solar system via impact.

An insight into the occurrence of suicides in jails of an Italian region.

The objective of this study is to explore the personal and environmental causes of suicides in jails of an Italian region, by evaluating the extent of the phenomenon, in order to devise strategies for prevention. The examined documentation deals with all cases of suicide among detainees in the 14 prisons of the region Lazio between 01/01/2008 and 31/12/2014. The factors considered for evaluation concerns the are socio-demographics (age, gender, nationality) as well as legal aspects, prison characteristics (type of crime, judicial state) and method used for the suicide. The results show that the method to commit suicide in prisoners of Lazio is hanged. Suicides occur especially in Italian prisoners. Most prison inmates commit suicide less than one year before the end of the detention period. Since the majority of risk factors for suicide are present before the subject enters prison, it is not easy to observe and check the prisoners once they are in jail. The evaluation of the prisoners should be done during the phase when they first enter the jail and not after the intervening variables associated with the detention have had their effects. This suggests that further studies are necessary to better understand the phenomenon and evaluate the possibility to introduce effective preventive measures.

Micrometeorites from the transantarctic mountains.

We report the discovery of large accumulations of micrometeorites on the Myr-old, glacially eroded granitic summits of several isolated nunataks in the Victoria Land Transantarctic Mountains. The number (>3,500) of large (>400 mum and up to 2 mm in size) melted and unmelted particles is orders of magnitudes greater than other Antarctic collections. Flux estimates, bedrock exposure ages and the presence of approximately 0.8-Myr-old microtektites suggest that extraterrestrial dust collection occurred over the last 1 Myr, taking up to 500 kyr to accumulate based on 2 investigated find sites. The size distribution and frequency by type of cosmic spherules in the >200-mum size fraction collected at Frontier Mountain (investigated in detail in this report) are similar to those of the most representative known micrometeorite populations (e.g., South Pole Water Well). This and the identification of unusual types in terms of composition (i.e., chondritic micrometeorites and spherulitic aggregates similar to the approximately 480-kyr-old ones recently found in Antarctic ice cores) and size suggest that the Transantarctic Mountain micrometeorites constitute a unique and essentially unbiased collection that greatly extends the micrometeorite inventory and provides material for studies on micrometeorite fluxes over the recent ( approximately 1 Myr) geological past.